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Cayenne
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Cayenne contains carotenoids and vitamins C and E; antioxidants that protect against free radicals, oxygen compounds that can damage cell membranes and disturb metabolic pathways. Consumption of carotenoids is associated with a reduced risk of cancer and enhances the activity of various immunesystem cells. The carotenoids in red peppers have been shown clinically to improve lifespan in primates.
Capsaicin, the source of cayenne's bite, is used in minute amounts in topical pharmaceutical products to treat pain at the site of an apparently healed infection, rheumatoid and osteoarthritis, and shingles. (The whole herb itself is not used in this way.)